Journal of the Chemical Society. Chemical communications p. 893 - 894 (1986)
Update date:2022-08-05
Topics:
Burdon, James
Price, Robin C.
Product analysis and deuterium labelling experiments suggest that the critical intermediate in the reduction of ArCOCH2R with Zn/HCl is a zinc-carbene; this may be protonated to give ArCH2CH2R, converted into ArCH=CHR by rearrangement, deprotonated to give a vinyl-zinc species, or captured by an alkene to give a cyclopropane.
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