Unprecedented observation of lactone hydrolysis by the A(Al)2 mechanism

DOI: 10.1016/S0040-4039(00)79916-3

Source and publish data:

Tetrahedron Letters p. 2331 - 2334 (1991)

Update date:2022-08-03

Topics:

Authors:

Moore Moore

Schwab Schwab

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Article abstract of DOI:10.1016/S0040-4039(00)79916-3

Five-membered lactones are shown to undergo exchange of the ring oxygen when heated at reflux in 6 N HCl/H₂¹⁸O. It is concluded that lactones can be hydrolyzed by the previously unreported A(Al)2 mechanism.

Full text of DOI:10.1016/S0040-4039(00)79916-3

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