TOTAL SYNTHESIS OF BENGAMIDE E

DOI: 10.1016/S0040-4039(00)74488-1

Source and publish data:

Tetrahedron Letters p. 1063 - 1066 (1991)

Update date:2022-08-03

Topics:

Authors:

Chida, Noritaka

Tobe, Takahiko

Ogawa, Seiichiro

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Article abstract of DOI:10.1016/S0040-4039(00)74488-1

The first total synthesis of bengamide E (1), a novel sponge-derived amino acid, is described.The side chain of bengamide E (2) possessing four contiguous chiral centers was prepared in a stereoselective manner starting from naturally abundant cyclitol, L-quebrachitol.

Full text of DOI:10.1016/S0040-4039(00)74488-1

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Product name:Acetic acid (E)-(R)-1-{(4S,5R)-5-[(R)-methoxy-((S)-2-oxo-azepan-3-ylcarbamoyl)-methyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-4-methyl-pent-2-enyl ester

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