Tetrahedron Letters p. 2285 - 2288 (1991)
Update date:2022-07-29
Topics:
Bowman, W. Russel
Brown, David S.
Chaffin, Julie D. E.
Symons, Martyn C. R.
Jackson, Stuart W.
Willcocks, Neil A.
Stereoselective oxidative addition of hydroxide anions to nitroalkenes was carried out using potassium ferricyanide to yield α-nitro-oxiranes by a novel non-chain mechanism involving cyclisation of alkoxide anions onto α-nitroalkyl radicals.
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