Catalytic Behavior of Rhodium(I) Complexes in Hydrogermylation and Hydrosilylation of Phenylacetylene

DOI: 10.1246/bcsj.64.1701

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1701 - 1703 (1991)

Update date:2022-08-05

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Authors:

Wada, Fumio

Abe, Seiji

Yonemaru, Norio

Kikukawa, Kiyoshi

Matsuda, Tsutomu

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Article abstract of DOI:10.1246/bcsj.64.1701

Rhodium complexes, Rh(L)(C2H4)2 , catalyze hydrogermylation and hydrosilylation of phenylacetylene with Bu3GeH and R3SiH (R=Bu, Et), respectively, to produce Ph(R3M)C=CH2 (M=Ge, Si) selectively.Other rhodium complexes, that is 2, Rh2Cl2(cod)2, Rh(tmhd)(C2H4)2 , and Rh(dbm)(C2H4)2 , also catalyze these reactions, but with less regioselectivity.

Full text of DOI:10.1246/bcsj.64.1701

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