Tetrahedron Letters p. 2197 - 2198 (1991)
Update date:2022-08-03
Topics:
Pegram, J. J.
Anderson, C. B.
(E,E)-1-Methoxy-4-trimethylsilyl-1,3-butadiene (1) was prepared from the R,S and S,R adducts of methoxymethyldiphenylphosphine oxide with trans-trimethylsilylpropenal.The (E,E)-dien (1) underwent facile Diels-Alder reaction with naphthoquinone and other dienophiles under mild conditions leading to cis-3-methoxy-6-trimethylsilylcyclohexene derivatives.
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