(E,E)-1-METHOXY-4-TRIMETHYLSILYL-1,3-BUTADIENE: A DIENE FOR THE DIELS-ALDER SYNTHESIS OF METHOXY-SUBSTITUTED ALLYL SILANES

DOI: 10.1016/S0040-4039(00)79678-X

Source and publish data:

Tetrahedron Letters p. 2197 - 2198 (1991)

Update date:2022-08-03

Topics:

Authors:

Pegram, J. J.

Anderson, C. B.

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Article abstract of DOI:10.1016/S0040-4039(00)79678-X

(E,E)-1-Methoxy-4-trimethylsilyl-1,3-butadiene (1) was prepared from the R,S and S,R adducts of methoxymethyldiphenylphosphine oxide with trans-trimethylsilylpropenal.The (E,E)-dien (1) underwent facile Diels-Alder reaction with naphthoquinone and other dienophiles under mild conditions leading to cis-3-methoxy-6-trimethylsilylcyclohexene derivatives.

Full text of DOI:10.1016/S0040-4039(00)79678-X

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