Preparation of C-Aryl Glucals via the Palladium-Catalyzed Coupling of Metalated Aromatics with 1-Iodo-3,4,6-tri-O-(triisopropylsilyl)-D-glucal

DOI: 10.1021/jo00016a003

Source and publish data:

Journal of Organic Chemistry p. 4821 - 4823 (1991)

Update date:2022-09-26

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Authors:

Friesen, Richard W.

Loo, Richard W.

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Article abstract of DOI:10.1021/jo00016a003

The preparation of the novel iodo glucal 5 from 3,4,6-tri-O-(triisopropylsilyl)-D-glucal (4), via a two-step procedure involving C1 stannylation and subsequent tin-iodine exchange, is described.The palladium-catalyzed coupling of 5 with a variety of metal

Full text of DOI:10.1021/jo00016a003

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Product name:1-C-(2-methylphenyl)-3,4,6-tri-O-(triisopropylsilyl)-D-glucal

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