Asymmetric induction in 8π electrocyclizations. Design of a removable chiral auxiliary

DOI: 10.1021/ol202932x

Source and publish data:

Organic Letters p. 138 - 141 (2012)

Update date:2022-08-02

Topics:

Authors:

Kim, Keunsoo

Lauher, Joseph W.

Parker, Kathlyn A.

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Article abstract of DOI:10.1021/ol202932x

The pseudo C₂ symmetric trans diphenyl oxazoline group acts as an effective chiral auxiliary in the 8π, 6π tandem electrocyclization of a substituted tetraene 1-carboxylic acid. Assignment of absolute stereochemistry to the [4.2.0] bicyclooctad

Full text of DOI:10.1021/ol202932x

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