Photolysis of Dioxiranes in the Presence of a Nitroxide Radical Scavenger: The Intermediacy of Radical Anion and Diyl Species in the Production and Trapping of Methyl and Trifluoromethyl Radicals

DOI: 10.1039/c39910000771

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 771 - 773 (1991)

Update date:2022-07-30

Topics:

Authors:

Adam, Waldemar

Bottle, Steven E.

Mello, Rossella

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39910000771

Electron transfer between dioxiranes 1 and nitroxide 2 affords the dioxirane radical anion-oxoammonium cation pair, which generates methyl radicals that are trapped by the nitroxide.

Full text of DOI:10.1039/c39910000771

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1,1,3,3-Tetramethyl-2-trifluoromethoxy-2,3-dihydro-1H-isoindole

Cas No:135248-48-5

R&D Labs maybe for 135248-48-5

Hubei Xinghuo Chemical Co., Ltd.,

Contact:13925817279 13907299441

Address:Xinghuo Fine Chemistry Industrial Park, Xiaochang County, Hubei Province, China
Taizhou volsen chemical Co., Ltd

website:http://www.volsenchem.com

Contact:+86-576-88869393

Address:Jiaojiang District, Taizhou, Zhejiang, China.
SHANGHAI T&W PHARMACEUTICAL CO., LTD.

website:http://www.trustwe.com

Contact:+86-21-61551413

Address:601, No. 1, 2277 Nong, Zu Chongzhi Road, Zhangjiang Hightech. Park, Pudong
Reliable Pharma Technology (Shanghai) Co., Ltd.

Contact:0086-21-67676847-8008

Address:Lane 1500, No.68, Xinfei Road, Songjiang District, Shanghai, 201611, P.R.China.
hangzhou sunchem trading co., ltd.

Contact:13588470430--

Address:Room 406-407, the 4th Building, No549

Relevant to this article

Optimization of the antioxidant activity of hydroxy-substituted 4-thiaflavanes: A proof-of-concept study

Doi:10.1002/chem.201101146
(2011)
Antiproliferative diarylpyrazole derivatives as dual inhibitors of the ERK pathway and COX-2

Doi:10.1111/cbdd.12186
(2013)
Synthesis and antibacterial activity of betulonic acid amides with piperazine derivatives

Doi:10.1007/s10600-011-0051-x
(2011)
Asymmetric Michael addition reactions of 3-substituted benzofuran-2(3H)- ones to nitroolefins catalyzed by a bifunctional tertiary-amine thiourea

Doi:10.1039/c1ob06518a
(2012)
N-NITROHYDRAZINES AND THEIR SALTS

Doi:10.1007/BF00961361
(1991)
Microwave assisted synthesis of 4-methyl-3-arylpyrano[2,3-f]chromen-2(8H)-one derivatives, evaluation of antiproliferative, and antimicrobial activities

Doi:10.1002/jhet.4103
(2020)

Article Doi