Photolysis of Dioxiranes in the Presence of a Nitroxide Radical Scavenger: The Intermediacy of Radical Anion and Diyl Species in the Production and Trapping of Methyl and Trifluoromethyl Radicals

DOI: 10.1039/c39910000771

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 771 - 773 (1991)

Update date:2022-07-30

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Authors:

Adam, Waldemar

Bottle, Steven E.

Mello, Rossella

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Article abstract of DOI:10.1039/c39910000771

Electron transfer between dioxiranes 1 and nitroxide 2 affords the dioxirane radical anion-oxoammonium cation pair, which generates methyl radicals that are trapped by the nitroxide.

Full text of DOI:10.1039/c39910000771

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