THE MICHAEL REACTION OF 2-(PHENYLTHIO)-2-PENTEN-5-OLIDE WITH SOME BENZYLIC GRIGNARD REAGENTS. SYNTHESIS OF SECOCRISPIOLIDE

DOI: 10.1246/cl.1984.1697

Source and publish data:

Chemistry Letters p. 1697 - 1700 (1984)

Update date:2022-08-05

Topics:

Authors:

Kato, Michiharu

Ouchi, Akihiko

Yoshikoshi, Akira

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Article abstract of DOI:10.1246/cl.1984.1697

The electrophilic reactivity of 2-(phenylthio)-2-penten-5-olide toward some benzylic Grignard reagents was investigated, and 2-methylene-3-(2,6-dimethylbenzyl)-5-pentanolide (secocrispiolide) was synthesized from one of the Michael adducts.

Full text of DOI:10.1246/cl.1984.1697

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