THE MICHAEL REACTION OF 2-(PHENYLTHIO)-2-PENTEN-5-OLIDE WITH SOME BENZYLIC GRIGNARD REAGENTS. SYNTHESIS OF SECOCRISPIOLIDE

DOI: 10.1246/cl.1984.1697

Source and publish data:

Chemistry Letters p. 1697 - 1700 (1984)

Update date:2022-08-05

Topics:

Authors:

Kato, Michiharu

Ouchi, Akihiko

Yoshikoshi, Akira

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1984.1697

The electrophilic reactivity of 2-(phenylthio)-2-penten-5-olide toward some benzylic Grignard reagents was investigated, and 2-methylene-3-(2,6-dimethylbenzyl)-5-pentanolide (secocrispiolide) was synthesized from one of the Michael adducts.

Full text of DOI:10.1246/cl.1984.1697

Products guided by the article

Product name:3-Benzyl-2-phenylthio-5-pentanolide

Cas No:135253-21-3

R&D Labs maybe for 135253-21-3

Hubei Vanz Pharm Co.,Ltd

website:http://www.vanzpharm.com/en/index.html

Contact:86-27-84492310

Address:FANHU INDUSTRY PARK
Hybio Pharmaceutica Co.,Ltd

Contact:+86 755 26588093

Address:No.9 Linkong West Street, Hengdian Street, Huangpi District, Wuhan City, China.
JinTan Pingsheng Chemical Co.,Ltd

Contact:+86-519-82828200

Address:NO.11Danfengxilu Road,Jintan City,Jiangsu,China
Dragon Chemical Co., Ltd.

Contact:0571-

Address:zhejing
Jinan YouCheng Pharmatech Co.,Ltd

Contact:+86-18653163205

Address:No.750, Shunhua Road, University Science Park, High-tech Zone, Jinan City

Relevant to this article

Synthesis of (-)-dihydropinidine, (2S,6R)-isosolenopsin and (+)-monomorine via a chiral synthon from l-aspartic acid

Doi:10.1016/j.tetasy.2011.11.006
(2011)
Photoinduced chlorine atom-transfer cyclization/photohydrolysis of 3-acyl-2-chloro-N-(ω-phenylalkynyl)pyrroles: A one-pot synthesis of benzoyl-substituted fused pyrroles

Doi:10.1039/c1ob05954h
(2012)
Selective reduction of formamides to O-silylated hemiaminals or methylamines with HSiMe₂Ph catalyzed by iridium complexes

Doi:10.1039/c8dt05070h
(2019)
Oligo(p-phenylene ethynylene)-BODIPY derivatives: Synthesis, energy transfer, and quantum-chemical calculations

Doi:10.1002/chem.201100454
(2011)
Heteroaromatic analogues of 1,5-diarylpyrazole class as anti-inflammatory agents

Doi:10.1007/s00044-011-9898-4
(2012)
Expeditious diastereoselective construction of a thiochroman skeleton via a cinchona alkaloid-derived catalyst

Doi:10.1039/c1ob06497e
(2012)

Article Doi