A facile synthesis of 1,5-dienes by a regioselective allylation of the allylic arbanions generated from allyl phenyl selenides

DOI: 10.1248/cpb.40.288

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 288 - 290 (1992)

Update date:2022-08-05

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Authors:

Nishitani

Mimaki Mimaki

Sato Sato

Yamakawa

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Article abstract of DOI:10.1248/cpb.40.288

Allyl-allyl or benzyl coupling reactions were effected by allyl carbanions, generated from allyl phenyl selenides and n-butyllithium, and allylic or benzylic halides. The ambident selectivities of the allyl carbanions are depending on the solvent system.

Full text of DOI:10.1248/cpb.40.288

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