Tetrahedron Letters p. 2387 - 2390 (1991)
Update date:2022-07-30
Topics: [3,3]-sigmatropic rearrangement Pericyclic Reactions
Harano, Kazunobu
Ono, Kikuma
Nishimoto, Mitsuhiro
Eto, Masashi
Hisano, Takuzo
Thermolysis of O-(2,4-alkadienyl) S-(2-alkenyl or 2-alkynyl) dithiocarbonates (xanthates) gave the hydroisobenzothiophene derivatives via two sequential <3,3>-sigmatropic rearrangment followed by the intramolecular cycloaddition.
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(1991)
