Organometallics p. 2930 - 2936 (1991)
Update date:2022-08-04
Topics:
Choi, Heajin
Hershberger, James W.
Pinhas, Allan R.
Ho, Douglas M.
The nickel-promoted isomerization of a 3-vinylcyclobutene to the corresponding 1,4-cyclohexadiene was studied by using (PPh3)2Ni(C2H4) as the nickel source. Through the use of chemical and electrochemical experiments, it was determined that nickel(I) and not nickel(0) promotes this isomerization reaction at room temperature. The corresponding platinum-vinylcyclobutene complex 4 has been characterized by a single-crystal X-ray diffraction study: C46H42O4P2Pt, monoclinic, P21/n, with a = 10.774 (1) ?, b = 20.281 (4) ?, c = 18.297 (2) ?, β = 97.37 (1)°, Z = 4, R(F) = 0.0378, and Rw(F) = 0.0371.
Contact:+86+21-58956006 15800617331
Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai
Quhua Zhongxing Refrigeration Technology Co.,Ltd.
Contact:+86-5708886618
Address:318 Bulding 2, No.866 Quhua Rd.,Kecheng District
Contact:+86-025-52406782
Address:8 Taizishan Rd., Yanjiang Industrial Development Area, Nanjing, Jiangsu, China.
Contact:+86-710-3516804
Address:Number 83,Panggong road,Xiangcheng District,Xiangyang ,Hubei
website:http://www.jairadhesales.com
Contact:0091-79-26431096
Address:309 Harikrupa Tower,Nr old Sharda Mandir Char Rasta,Ellisbridge
Doi:10.1039/c3dt52133h
(2014)Doi:10.1016/S0040-4020(01)87110-6
(1991)Doi:10.1021/ol2033916
(2012)Doi:10.1021/jo202336y
(2012)Doi:10.1002/anie.201105516
(2012)Doi:10.1021/acsmedchemlett.9b00152
(2019)
