Regioselective alkylation of 1-silyl-2-methylallyl carbanions

DOI: 10.1016/0040-4039(91)80637-L

Source and publish data:

Tetrahedron Letters p. 2879 - 2882 (1991)

Update date:2022-07-30

Topics:

Authors:

Wang d. Wang d.

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Article abstract of DOI:10.1016/0040-4039(91)80637-L

Regioselective alkylations of 1-silyl-2-methylallyl carbanions were achieved by changing the substituents on silicon. γ-Alkylation was favoured by dialkylamino group on silicon, whereas α-alkylation was favoured by an alkoxy substituent on silicon.

Full text of DOI:10.1016/0040-4039(91)80637-L

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