Synthesis of Substituted Furans by Palladium-Catalyzed Cyclization of Acetylenic Ketones

DOI: 10.1021/jo00020a024

Source and publish data:

Journal of Organic Chemistry p. 5816 - 5819 (1991)

Update date:2022-08-03

Topics:

Authors:

Fukuda, Yukitoshi

Shiragami, Hiroshi

Utimoto, Kiitiro

Nozaki, Hitosi

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Article abstract of DOI:10.1021/jo00020a024

Palladium-catalyzed cyclization of β,γ-acetylenic ketones gives furans by intramolecular oxypalladation and subsequent protodemetalation. 3-Allylfurans were exclusively obtained by trapping the intermediate 3-furylpalladium species with allyl halides in t

Full text of DOI:10.1021/jo00020a024

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