ACYCLIC DIASTEREOFACIAL SELECTION IN RADICAL ADDITION.

Article abstract of DOI:10.1016/S0040-4039(00)79767-X

1,2-Asymmetric induction with up to 83 percent of diastereoisomeric excess has been observed during intermolecular addition of silicon centered radical to carbon-carbon double bond of chiral non-racemic α,β-unsaturated esters derived from glyceraldehyde a