Russian Chemical Bulletin p. 1540 - 1543 (2000)
Update date:2022-08-03
Topics:
Kurtikyan
Stepanyan
Martirosyan
Kazaryan
Madakyan
The low-temperature interaction of sublimed layers of manganese(II) meso-tetraphenylporphyrinate (MnTPP) with O2, which has previously been observed only in solutions and in an inert gas matrix, was found by electron absorption and IR spectroscopy. The coordination of O2 with sublimed MnTPP layers is only partially reversible. Bands that can serve as IR-spectral markers characteristic of the high-spin Mn11 ion in MnTPP and its axial complexes were observed.
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