Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 951 - 954 (1991)
Update date:2022-08-02
Topics:
Shtamburg, V. G.
Rudchenko, V. F.
Grinev, V. M.
Dmitrenko, A. A.
Pleshkova, A. P.
Kostyanovskii, R. G.
The addition of N-chloro-N-methoxy-tert-alkylamines to an olefin, which is assumed to proceed with the participation of alkoxynitrenium ions, was carried out for the first time.The methanolysis of N-chloro-N-alkoxy-tert-alkylamines in the presence of Et3N gives dialkoxyamines, and depending on the type of the N-alkyl substituent is accompanied by side reactions.
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