Reduction of molybdenum imido-alkylidene complexes in the presence of olefins to give molybdenum(IV) complexes

DOI: 10.1021/om00054a068

Source and publish data:

Organometallics p. 2902 - 2907 (1991)

Update date:2022-08-05

Topics:

Authors:

Robbins, Jennifer

Bazan, Guillermo C.

Murdzek, John S.

O'Regan, Marie B.

Schrock, Richard R.

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Article abstract of DOI:10.1021/om00054a068

Mo(CH-t-Bu)(NAr)[OCMe(CF₃)₂]₂ (1a) (Ar = 2,6-diisopropylphenyl) reacts with excess vinyltrimethylsilane to give Mo(NAr)[OCMe(CF₃)₂]₂(CH₂=CHSiMe ₃) (2) Complex 2 reacts

Full text of DOI:10.1021/om00054a068

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