Tetrahedron Letters p. 2715 - 2718 (1991)
Update date:2022-07-30
Topics:
Shea, K. J.
Staab, Andrew J.
Zandi, Kathleen S.
New methodology is reported which enables reversal of regiochemistry in the Diels-Alder reaction.Esterification of 2-(β-hydroxyethyl)dimethylsilyldienes with common dienophiles followed by type 2 intramolecular Diely-Alder reaction results in formation of a single regio- and stereoisomer.Oxidative cleavage of the cycloadduct produces a cyclohexanone with a substitution pattern opposite of that found in the analogous bimolecular cycloaddition reaction.
View MoreMollt Biochem Co., Ltd(expird)
Contact:+86-21-38682181
Address:shanghai ,china
Changzhou Anyi Biochem Co., Ltd.(expird)
Contact:+86-519-88836158
Address:no,51 caoda
Haitong Chemical Industrial Co.,Ltd.
website:https://www.haitonglongwin.com/
Contact:+86-022-66221018
Address:18-701, No.99, The 4th Street, TEDA,
website:http://www.apeptides.com/en/
Contact:+86-21-60871011
Address:No. 80 Chuanshan Shuyuan Steet,Pudong,Shanghai
Shandong Wanda Organosilicon New Material Co., Ltd
Contact:+86-21-54177116;54302881
Address:R1318 Greenland No. 3 Lane 58 Xinjian East Rd., Minhang
Doi:10.1021/acs.joc.5b02914
(2016)Doi:10.1007/s11164-012-0489-x
(2012)Doi:10.1016/j.jorganchem.2011.11.035
(2012)Doi:10.3390/ph14010010
(2021)Doi:10.1021/jo202553a
(2012)Doi:10.1016/S0040-4039(00)91679-4
(1992)
