Tetrahedron Letters p. 2715 - 2718 (1991)
Update date:2022-07-30
Topics:
Shea, K. J.
Staab, Andrew J.
Zandi, Kathleen S.
New methodology is reported which enables reversal of regiochemistry in the Diels-Alder reaction.Esterification of 2-(β-hydroxyethyl)dimethylsilyldienes with common dienophiles followed by type 2 intramolecular Diely-Alder reaction results in formation of a single regio- and stereoisomer.Oxidative cleavage of the cycloadduct produces a cyclohexanone with a substitution pattern opposite of that found in the analogous bimolecular cycloaddition reaction.
View MoreSHIJIAZHUANG AGERUO-BIOTECH CO.LTD
Contact:+86-130-2866-6699
Address:Huaian east Road 158
Tianjin Realet Chemical Technology Co.,Ltd.
website:http://www.realetchem.com
Contact:+86-022-58788819
Address:shuanggang industrial park
Contact:+86-27-67841589
Address:Add: 999 Gaoxin Road, Donghu New Technology Development Zone, Wuhan City, Hubei, China
Zhejiang Kaili Industrial Co., Ltd
Contact:+86-571-85241926
Address:lantian business center,No.18 Moganshan Road
Contact:027-87677569
Address:Room 2203, yujingmingmen Buidling One, xiongchu Road, wuhan city, hubei province, China
Doi:10.1021/acs.joc.5b02914
(2016)Doi:10.1007/s11164-012-0489-x
(2012)Doi:10.1016/j.jorganchem.2011.11.035
(2012)Doi:10.3390/ph14010010
(2021)Doi:10.1021/jo202553a
(2012)Doi:10.1016/S0040-4039(00)91679-4
(1992)
