Zeitschrift fur Anorganische und Allgemeine Chemie p. 220 - 223 (2012)
Update date:2022-08-04
Topics:
Rofouei, Mohammad Kazem
Attar Gharamaleki, Jafar
Fereyduni, Ehsan
Aghaei, Aboulfazl
Bruno, Giuseppe
Rudbari, Hadi Amiri
The reaction of [1, 3-bis(2-ethoxy)benzene]triazene, [HL], with Hg(SCN)2 and Hg(CH3COO)2, resulted in the formation of the complexes [HgL(SCN)] (1) and [HgL2]·CH 3OH (2). They were characterized by means of X-ray crystallography, CHN analysis, FT-IR, 1H NMR, and 13C NMR spectroscopy. The structure of compound 1 consists of two independent complexes in which the HgII atoms are stacked along the crystallographic a axis to form infinite chains. Each HgII atom is chelated by one L ligand and one SCN ligand, whereas in compound 2, the HgII atom is surrounded by two L ligands. In addition, 1D chains formed by metal-π interactions are connected to each other by C-H...π stacking interactions in the structure of 1, which results in a 2D architecture. An interesting feature of compound 2 is the presence of C-H...π edge-to-face interactions. Copyright
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