Reaction of E-1,2-bis[triphenyl(trifluoromethanesulfonyloxy)phospho]ethylene, Ph3PCH=CHPPh3·20Tfwith bases: Unusual products and evidence for C2-dlylide, Ph3P=C=C=PPh3, formation

DOI: 10.1016/S0040-4020(01)86460-7

Source and publish data:

Tetrahedron p. 4539 - 4546 (1991)

Update date:2022-08-04

Topics:

Authors:

Stang, Peter J.

Arif, Atta M.

Zhdankin, Viktor V.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)86460-7

E-1,2-di[triphenyl(trifluoromethanesulphonyloxy)phospho]ethylene 4 reacts with Et₃N or NaH in wet CH₃CN affording phosphineoxides 6 and 7 as a result of phenyl migration and related rearrangements in hydrolysed phosphonium moieties.

Full text of DOI:10.1016/S0040-4020(01)86460-7

Products guided by the article

Product name:1--2--1-phenylethane

Cas No:136151-78-5

R&D Labs maybe for 136151-78-5

Advanced Biotech

Contact:+1-973-357-0577

Address:10 Taft Rd.
Zhejiang Kaili Industrial Co., Ltd

Contact:+86-571-85241926

Address:lantian business center,No.18 Moganshan Road
GenicBio Limited

Contact:+86-(0)21-3770 9035

Address:Room 301, Building 2, Meijiabang Road 1508, Shanghai China
Fujian Huitian Biological Pharmacy Co., Ltd.

Contact:0086-598-8300831; 8339920

Address:No.46,Taijiang Road,Sanming City,Fujian,China
NingBO Hong Xiang Biochem.Co.Ltd

website:http://www.hxbiochem.com

Contact:0574-66003444

Address:Ning Bo Bei Lun

Relevant to this article

First synthesis of diindeno[1,2-g:1′,2′-s]rubicene derivatives and their evaluation as semiconductors

Doi:10.1071/CH11375
(2012)
High-Pressure Induced 1,3-Dipolar Cycloadditions of Azides with Electron-Deficient Olefins

Doi:10.1021/jo00024a047
(1991)
Facile (triazolyl)methylation of MACOS-derived benzofused sultams utilizing ROMP-derived OTP reagents

Doi:10.1021/co2001839
(2012)
Synthesis, biological evaluation and molecular investigation of fluorinated peroxisome proliferator-activated receptors α/γ dual agonists

Doi:10.1016/j.bmc.2012.01.025
(2012)
Synthesis and evaluation of cytotoxic effects of novel α- methylenelactone tetracyclic diterpenoids

Doi:10.1016/j.bmcl.2012.01.051
(2012)
Synthesis of fluorinated biaryl derivatives via S_RN1 reactions

Doi:10.1016/0040-4039(91)80813-L
(1991)

Article Doi