Copper-Catalyzed Reactions of Organotitanium Reagents. Highly SN2'- and Anti-Selective and Diastereo- and Chemoselective Alkylation of Allylic Chlorides and Phosphates

DOI: 10.1021/jo00019a001

Source and publish data:

Journal of Organic Chemistry p. 5489 - 5491 (1991)

Update date:2022-07-30

Topics:

Authors:

Arai, Masayuki

Nakamura, Eiichi

Lipshutz, Bruce H.

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Article abstract of DOI:10.1021/jo00019a001

Organotitanium reagents undergo Cu(I)-catalyzed S_N2' substitution reactions with allylic chlorides and phosphates in a regio-, stereo-, and chemoselective manner: in the presence of Me3SiCl or Me3SiOSO2CF3, they undergo preferential conjugate addition to enones.

Full text of DOI:10.1021/jo00019a001

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