Journal of Organic Chemistry p. 5489 - 5491 (1991)
Update date:2022-07-30
Topics:
Arai, Masayuki
Nakamura, Eiichi
Lipshutz, Bruce H.
Organotitanium reagents undergo Cu(I)-catalyzed SN2' substitution reactions with allylic chlorides and phosphates in a regio-, stereo-, and chemoselective manner: in the presence of Me3SiCl or Me3SiOSO2CF3, they undergo preferential conjugate addition to enones.
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