Preferred Conformation of C-Glycosides. 6. Conformational Similarity of Glycosides and Corresponding C-Glycosides

Article abstract of DOI:10.1021/jo00022a038

The conformation of the α-(axial)-C-glycosides 1-3 and the β-(equatorial)-C-glycosides 4-6 were studied by 1H NMR.Their preferred solution conformation was found to match that of the corresponding parent glycosides.The study of 2-deoxy compounds 13-16 sho