Stereoselective addition of allylstibonium bromide to aldehydes

DOI: 10.1016/0022-328X(91)86040-W

Source and publish data:

Journal of Organometallic Chemistry p. 47 - 52 (1991)

Update date:2022-07-30

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Authors:

Huang, Yao-Zeng

Zhang, Li-Jun

Chen, Chen

Guo, Guang-Zhong

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Article abstract of DOI:10.1016/0022-328X(91)86040-W

Reaction of allylantimony with aldehydes provides homoallylic alcohols with high threo selectivity in the case of (E)-4-methyl-2-pentenylantimony (2c) and with preferential erythro selectivity in the case of crotylantimony (2a).

Full text of DOI:10.1016/0022-328X(91)86040-W

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