Remote Asymmetric Induction in Diastereoface Selective Addition Reactions of Optically Active α-Substituted-β-silyl (E)-Hexenoates with Achiral α-Alkoxy and β-Alkoxy Acetals

DOI: 10.1021/jo00020a009

Source and publish data:

Journal of Organic Chemistry p. 5755 - 5758 (1991)

Update date:2022-08-04

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Authors:

Panek, James S.

Yang, Michael

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Article abstract of DOI:10.1021/jo00020a009

Optically active and diastereomerically pure (E)-crotylsilanes 1 function as effective chiral carbon nucleophiles in trimethylsilyl trifluoromethanesulfonate (TMSOTf) catalyzed asymmetric addition reactions of achiral, α-alkoxy and β-alkoxy acetals 2, res

Full text of DOI:10.1021/jo00020a009

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Product name:(E)-(2S,5R,6R)-7-Benzyloxy-2,6-dimethoxy-5-methyl-hept-3-enoic acid methyl ester

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