
Journal of the Chemical Society. Perkin transactions I p. 1623 - 1627 (1996)
Update date:2022-09-26
Topics:
Butler, Richard N.
Lysaght, Fiona A.
McDonald, Peter D.
Pyne, Carmel S.
McArdle, Patrick
Cunningham, Desmond
A range of new fused ring systems based on phenanthrene were obtained from cycloaddition-rearrangement reactions of 9,10-bisarylazophenanthrenes with alkyne and alkene dipolarophiles. These new rings include substituted phenanthro[9,10-e]-1,2,3-triazines, the tricyclic systems, substituted 3a,6a-(biphen-2,2′-yl)hexahydropyrrolo[2,3-d]-1,2,3-triazoles and substituted 3a,6a-(biphen-2,2′-yl)-hexahydroimidazo[4,5-d]-1,2,3-triazoles. X-Ray crystal structures are reported on 2-(p-bromophenyl)-4-methoxycarbonyl-4-(p-bromophenyliminomethoxalyl)-3,4- dihydrophenanthro[9,10-e]-1,2,3-triazin-2-ium-3-ide 6b, and 2,4-diphenyl-3a,6a-(biphen-2,2′-yl)-5,6-endo-dicarboxy-N-phenylimido)-1, 3a,4,5,6,6a-hexahydropyrrolo[2,3-d]-1,2,3-triazol-2-ium-1-ide 11a.
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