Reductive Deacetoxylation of allylic Acetates Using Hexacarbonylmolybdenum(0)

DOI: 10.1246/bcsj.64.2311

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2311 - 2313 (1991)

Update date:2022-09-26

Topics:

Authors:

Masuyama, Yoshiro

Maekawa, Kazunobu

Kurihara, Toshiyuki

Kurusu, Yasuhiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.64.2311

Aliphatic allylic acetates were reduced to alkenes with hexacarbonylmolybdenum(0) in refluxing dioxane under nitrogen atmosphere.These reactions were accelerated by the addition of H2O. 1-Aryl- or 3-arylallyl acetates caused deacetoxylative allylic homocoupling under the same conditions.

Full text of DOI:10.1246/bcsj.64.2311

Products guided by the article

Product name:3,4-dibutyl-1,6-diphenyl-1,5-hexadiene

Cas No:136272-14-5

R&D Labs maybe for 136272-14-5

Shanghai Maxchemco Chemical Industry Co., Ltd.

Contact:(86)21-51079223

Address:No.1305-8, B241, the Ecust Park, Huajing Road, Xuhui District, Shanghai
Zibo Fuxi'er Chemical Co.,Ltd （Shanxian Fuxi'er Chemical Co.,Ltd）

Contact:+86-533-2091422

Address:Eastern 4 on the 3th Road ,Liangxiang Industrial Park, Zibo city ,Shandong,China
FOSHAN NANHAI ZHONGNAN PHARMACEUTICAL FACTORY

Contact:0086-0757-85609331

Address:XIAHENGTIAN INDUSTRIAL ZONE,SHAYONG VILLAGE,LISHUI TOWN
ChangZhou XiaQing Chemical Co., Ltd.

Contact:+86-519-88721665

Address:3# Hengluo Road, Henglin Town, Changzhou City, Jiangsu Province，China
Hangzhou Taiyan Trading Co., Ltd(expird)

Contact:+86-13777583958

Address:NO.63, Xingyi Street, Xihu District, Hangzhou, Zhejiang, China

Relevant to this article

Regiospecific α-Substitution of Crotonic Esters. Synthesis of Naturally Occurring Derivatives of 6-Ethyljuglone

Doi:10.1016/S0040-4020(01)87099-X
(1991)
New efficient synthesis of 5,6-disubstituted-3-phenyl-1,2,3-triazolo[4,5-d] pyrimidin-7-ones via a tandem aza-Wittig reaction

Doi:10.1080/00397911.2010.535940
(2012)
Palladium-catalyzed ullmann-type reductive homocoupling of iodoaryl glycosides

Doi:10.1021/jo2025652
(2012)
Synthesis and functionalization of imidazo[1,2-a] pyridines and imidazo [1,2-a] pyrimidines on solid phase using suzuki-miyaura cross-coupling reactions

Doi:10.2174/157017812800221753
(2012)
Unusual Cu(I)-catalyzed 1,3-dipolar cycloaddition of acetylenic amides: Formation of bistriazoles

Doi:10.1016/j.tetlet.2012.01.069
(2012)
Catalytic diastereoselective synthesis of cis-1,2-disubstituted cyclopropanols from esters using a vicinal dicarbanion equivalent

Doi:10.1021/ja00099a068
(1994)

Article Doi