Reductive Deacetoxylation of allylic Acetates Using Hexacarbonylmolybdenum(0)

DOI: 10.1246/bcsj.64.2311

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2311 - 2313 (1991)

Update date:2022-09-26

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Authors:

Masuyama, Yoshiro

Maekawa, Kazunobu

Kurihara, Toshiyuki

Kurusu, Yasuhiko

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Article abstract of DOI:10.1246/bcsj.64.2311

Aliphatic allylic acetates were reduced to alkenes with hexacarbonylmolybdenum(0) in refluxing dioxane under nitrogen atmosphere.These reactions were accelerated by the addition of H2O. 1-Aryl- or 3-arylallyl acetates caused deacetoxylative allylic homocoupling under the same conditions.

Full text of DOI:10.1246/bcsj.64.2311

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