Stereoselective synthesis of alkyl α-(1,3-alkadien-2-yl)acetates and -propionates by allene Claisen rearrangement

DOI: 10.1055/s-1991-26534

Source and publish data:

Synthesis p. 644 - 646 (1991)

Update date:2022-07-29

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Authors:

Behrens Behrens

Wolff Wolff

Hoppe Hoppe

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Article abstract of DOI:10.1055/s-1991-26534

Configurationally homogeneous (4-hydroxy-1,2-alkadienyl) N,N-diisopropylcarbamates react with trialkyl orthocarboxylates to afford the title compounds stereoselectively. Stereochemical assignment of the highly substituted 1,3-alkadienes is accomplished NM

Full text of DOI:10.1055/s-1991-26534

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