Alkylpalladium(II) species. Reactive intermediates in a bis-cyclisation route to strained polyfused ring systems

DOI: 10.1016/S0040-4039(00)79396-8

Source and publish data:

Tetrahedron Letters p. 3855 - 3858 (1991)

Update date:2022-07-29

Topics:

Authors:

Grigg Grigg

Sridharan

Sukirthalingam

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Article abstract of DOI:10.1016/S0040-4039(00)79396-8

4-Alkenyl-allylic and-vinylic acetates or bromides undergo Pd(0) catalysed bis-cyclisation via an initial 5- or 6-exo-trig ring closure generating an alkylpalladium(II) intermediate which reacts further via a 3-, 4- or 5-exo-trig cyclisation onto a proxim

Full text of DOI:10.1016/S0040-4039(00)79396-8

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