Bulletin of the Chemical Society of Japan p. 2109 - 2117 (1991)
Update date:2022-08-04
Topics:
Yamada, Tohru
Takai, Toshihiro
Rhode, Oliver
Mukaiyama, Teruaki
The presence of a bis(1,3-diketonato)nickel(II) complex, various olefins are directly monooxygenated into the corresponding epoxides on treatment with atmospheric pressure of oxygen or air and aldehydes.Especially, it is noted that bis<1,3-bis(p-methoxyphenyl)-1,3-propanedionato>nickel(II) behaves as an excellent catalyst in the present epoxidation.
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