Chemistry Letters p. 1433 - 1436 (1991)
Update date:2022-08-05
Topics: Protonation Oxidative Addition Reductive Elimination Carbonylation
Satoh, Ko-ichi
Watanabe, Jun
Takaki, Ken
Fujiwara, Yuzo
The reactions of cycloalkanes with CO via the C-H bond activation by Pd(OAc)2 catalyst have been found to proceed regio- and stereo-selectively to give corresponding carboxylic acids.The reactivity of C-H bonds of cycloalkanes decreases in the order: tert- > sec- > prim-carbon, and the stereochemistry of the substitutents on the main products is all equatorial.
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Doi:10.1021/ol3004436
(2012)Doi:10.3762/bjoc.7.186
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(2012)Doi:10.1016/S0040-4039(00)79406-8
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(2012)Doi:10.1016/0040-4039(91)80626-H
(1991)
