Chemo-, Regio-, and Stereoselective Copper(II)-Catalyzed Boron Addition to Acetylenic Esters and Amides in Aqueous Media

DOI: 10.1021/acs.joc.6b00648

Source and publish data:

Journal of Organic Chemistry p. 4269 - 4279 (2016)

Update date:2022-07-29

Topics:

Authors:

Nelson, Amanda K.

Peck, Cheryl L.

Rafferty, Sean M.

Santos, Webster L.

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Article abstract of DOI:10.1021/acs.joc.6b00648

Aqueous conditions were developed for conducting an open-to-air, copper(II)-catalyzed addition of pinBBdan to alkynoates and alkynamides. The simple and mild β-borylation protocol proceeds in a remarkably chemo-, regio-, and stereoselective fashion to aff

Full text of DOI:10.1021/acs.joc.6b00648

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