Bulletin of the Chemical Society of Japan p. 3538 - 3543 (1991)
Update date:2022-07-30
Topics:
Kumura, Hiromi
Nakamura, Tomoyuki
Higuchi, Yoshiki
Suyama, Shuji
Diperoxy esters having a benzophenone chromophore have been successfully synthesized from the reaction of 3-chloro-3-phenylphthalide (1) with 2,5-dihydroperoxy-3-hexyne (4a) or 2,5-dihydroperoxy-2,5-dimethylhexane (4b).The corresponding diperoxy esters had a UV absorption above 300 nm.The free radicals produced during the photolysis of those compounds initiated the radical polymerization of methyl methacrylate at room temperature under UV light.
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(1992)
