Palladium-Mediated Cyclization of 1,5-Hexadien-3-ols to 1-Methyl-1,3-cyclopentadienes

DOI: 10.1016/0040-4039(91)80023-Y

Source and publish data:

Tetrahedron Letters p. 4501 - 4502 (1991)

Update date:2022-08-02

Topics: Yield Palladium Cyclization Reaction Conditions Catalysis

Authors:

Zair, Touriya

Santelli-Rouvier, Christiane

Santelli, Maurice

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Article abstract of DOI:10.1016/0040-4039(91)80023-Y

Treatment of 1-allyl-2-alkenylidenecyclohexanols in acetic acid by the Pd(0) complex led to 8-methyl bicyclo<4.3.0>nona-1(6),7-dienes.In contrast, only few examples of cyclization vs elimination were observed in acyclic 1,5-hexadien-3-ols.Keyw

Full text of DOI:10.1016/0040-4039(91)80023-Y

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