Transmetalation Reactions of Alkylzirconocenes: Copper-Catalyzed Conjugate Addition to Enones

DOI: 10.1021/jo00023a006

Source and publish data:

Journal of Organic Chemistry p. 6494 - 6496 (1991)

Update date:2022-08-03

Topics:

Authors:

Wipf, Peter

Smitrovich, Jacqueline H.

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Article abstract of DOI:10.1021/jo00023a006

Rapid hydrozirconation of alkenes by zirconocene hydrochloride, followed by addition of 1 equiv of enone and catalytic amounts of Cu(I) salts, led to the corresponding 1,4-addition products in moderate to high yields and provided the first protocol for in situ preparation of alkyl cuprates from alkenes.

Full text of DOI:10.1021/jo00023a006

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