Journal of Organic Chemistry p. 6494 - 6496 (1991)
Update date:2022-08-03
Topics:
Wipf, Peter
Smitrovich, Jacqueline H.
Rapid hydrozirconation of alkenes by zirconocene hydrochloride, followed by addition of 1 equiv of enone and catalytic amounts of Cu(I) salts, led to the corresponding 1,4-addition products in moderate to high yields and provided the first protocol for in situ preparation of alkyl cuprates from alkenes.
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