Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1425 - 1427 (1991)
Update date:2022-09-26
Topics:
Dzhemilev, U. M.
Ibragimov, A. G.
Morozov, A. B.
Muslukhov, R. R.
Tolstikov, G. A.
A novel approach was developed for the stereoselective synthesis of trans-3,4-dialkyl-substituted aluminacyclopentanes from α-olefins, metallic magnesium, and EtAlCl2 in the presence of catalytic amounts of Cp2ZrCl2.The hydrolysis and deuterolysis products of the 3,4-dialkyl-substituted aluminacyclopentanes obtained are only in the trans configuration.
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