Factors that cause contrasteric alkylation of a cyclopentane-1,2-dicarboxylic acid monoester

DOI: 10.1016/0040-4039(91)80034-4

Source and publish data:

Tetrahedron Letters p. 4541 - 4544 (1991)

Update date:2022-08-04

Topics:

Authors:

Kigoshi Kigoshi

Imamura Imamura

Yoshikawa

Niwa Niwa

Yamada Yamada

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Article abstract of DOI:10.1016/0040-4039(91)80034-4

The stereochemical outcome in the alkylation of the enolate generated from a cyclopentane-1,2-dicarboxylic acid monoester is described. The alkylation of the Li enolate with an ankylating reagent having a hard leaving group such as Cl gave a contrasteric

Full text of DOI:10.1016/0040-4039(91)80034-4

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