The conjugate addition of higher-order organocuprates to α-methoxyenones

DOI: 10.1016/0040-4039(91)80009-U

Source and publish data:

Tetrahedron Letters p. 4451 - 4452 (1991)

Update date:2022-08-04

Topics:

Authors:

Soderquist, John A.

Rosado, Izander

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(91)80009-U

The conjugate addition of higher-order organocuprates (Lipshutz reagents) at low temperature (-78° C) to α-methoxyenones (4) provides the corresponding β-substituted α-methoxy ketones (5) in 74-90% isolated yields.

Full text of DOI:10.1016/0040-4039(91)80009-U

Products guided by the article

Product name:2-Methoxy-1-phenyl-heptan-1-one

Cas No:137097-69-9

R&D Labs maybe for 137097-69-9

Nanjing Chemical Material Corp.(NCMC)

website:http://www.njchemm.com

Contact:0086-25-83172879

Address:B12 Technology and Innovation Building, Nanjing Tech University, No.5 New Model Road
NIGNXIA XINDACHANG TECHNOLOGY CO.,LTD

Contact:86-0951-7815345

Address:North side of Qiyuan Road, west side of Yuanfeng Highway, New Material Park, Ningdong Energy and Chemical Industry Base, Ningxia,China
Baoding City Light Industry And Textiles Imp.& Exp. Corp. Chemical Department.

Contact:86-312-3262436

Address:NO.658 CHAOYANG SOUTH STREET,BAODING CITY HEBEI CHINA
Shandong Yaroma Perfumery Co., Ltd.

Contact:+86- 531- 88024598

Address:7-702 Caizhi Central, 59 Gong Ye South Road, Jinan City,250101, P. R. China
SHANDONG ZHANHUA YONGHAO PHARMACEUTICAL TECH.CO.,LTD

Contact:+86-576-88685096

Address:GENGJU VILLAGE NORTH ONE KILOMETER,ZHANHUA DISTRICT,BINZHOU CITY,SHANDONG PROVINCE,CHINA.

Relevant to this article

Selective saccharide recognition using modular diboronic acid fluorescent sensors

Doi:10.1002/ejoc.201101633
(2012)
Ortho-carboxylate effects in copper-mediated nucleophilic substitution of halothiophenecarboxylic acids and halobenzoic acids with sodium bisulphite

Doi:10.1002/jccs.201190140
(2011)
Synthesis and synthetic applications of 1-aryl-2-alkyl-4,5-dihydro-1 H-imidazoles

Doi:10.1080/00397911.2011.552155
(2012)
Concise epoxide-based synthesis of the C14-C25 bafilomycin A₁ polypropionate chain

Doi:10.1016/j.tetlet.2012.02.067
(2012)
Synthesis and crystal structure of a copper(II) 5-sulfosalicylate complex with thiosemicarbazide

Doi:10.1134/S003602361204002X
(2012)
The use of sulfur ylides in the synthesis of 3-alkyl(aryl)thio-4- trifluoromethylpyrroles from mesoionic 4-trifluoroacetyl-1,3-oxazolium-5-olates

Doi:10.1016/j.tetlet.2012.03.130
(2012)

Article Doi