Journal of Organic Chemistry p. 7328 - 7331 (1991)
Update date:2022-07-30
Topics:
Lees, Watson J.
Singh, Rajeeva
Whitesides, George M.
meso-2,5-Dimercapto-N,N,N',N'-tetramethyladipamide (meso-DTA) reduces disulfide bonds up to 8 times faster (kinetic) than does dithiothreitol (DTT) in aqueous solution at pH 7.0. meso-DTA is easily synthesized in five steps (39percent overall yield) from adipic acid. meso-DTA, which forms a cyclic disulfide, is less reducing than DTT by approximately 56 mV, but is much more reducing than mercaptoethanol.
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