Organic and Biomolecular Chemistry p. 3715 - 3720 (2012)
Update date:2022-07-29
Li, Yaming
Liu, Jin
Xie, Yusheng
Zhang, Rong
Jin, Kun
Wang, Xiuna
Duan, Chunying
In this article, a facile, efficient and practical method for Ni-catalyzed direct C-H amination of benzoxazole with secondary amines has been developed. This procedure requires Ni(OAc)2·4H2O as catalyst, TBHP as oxidant and acid as the additive. A variety of substituted benzoxazol-2-amines were synthesized in moderate to good yields.
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Doi:10.1039/c2dt12322c
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(2012)
