Chirality recognition by 1,1'-binaphthyl-2,2'-diyl phosphoryl chloride - determination of configuration of asymmetric carbon atom attached to the hydroxy methylene group

Article abstract of DOI:10.1016/S0957-4166(00)80454-1

Chirality of the asymmetric carbon atom attached to the hydroxy methylene group can be determined with high sensitivity by derivation into the 1,1'-binaphthyl-2,2'-diyl phosphate [(R,S)-BNP ester]. Consistent result with the sign of the CD spectra and the