Tetrahedron Letters p. 5305 - 5308 (1991)
Update date:2022-08-03
Topics:
Haider
Clites
Berson
The biradical 2,5-dimethyl-3,4-dimethylenethiophene reacts with styrenes and benzaldehydes to give fused cycloadducts. The effect of substituents on the efficiency of the benzaldehyde trapping reaction resembles that of normal electron-demand Diels-Adler reactions and is linear with the Hammett σ-constant. With the styrenes, the Hammett plot is non-linear. Frontier orbital theory provides a rationalization of these effects in terms of the uniquely small HOMO-LUMO gap characteristic of biradicals.
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