Helvetica Chimica Acta p. 1600 - 1607 (1991)
Update date:2022-08-02
Topics: Diastereoselectivity Radical reactions Column chromatography NMR spectroscopy Enantioselectivity Steric hindrance Enantiomeric excess (ee) Recrystallization Stereoselective synthesis TLC (thin-layer chromatography) Protecting group Chiral Auxiliary Quenching Radical Initiation Radical intermediate Diastereomeric ratio (dr)
Bulliard, Michel
Zehnder, Margareta
Giese, Bernd
Radical addition to 2-cyclohexyl-5-methylidene-6-methyl-1,3-dioxan-4-one (2) affords stereoselectively 5,6-trans-products trans-3.The size of the radical has no influence on the selectivity.These trans-acetals are converted into threo-3-hydroxy-butanoates
View MoreFujian Wanke Pharmaceutical Co., LTD.
Contact:+86-598-5026002
Address:Economic development zone,jiangle county
Contact:+86-518-81061113
Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China
website:http://www.konochem.com
Contact:86-29-86107037
Address:No.170 West Avenue,Xi’an 710082,China
Shandong Xingshun New Material Co., Ltd.
website:http://www.sd-xingshun.com
Contact:+86-519-86461196
Address:Middle of Luhua East Road, Dingtao District
website:http://www.win-winchemical.com
Contact:0086-577-64498589
Address:6F, No. 396 Xingping Road, Longwan Industrial Zone, Wenzhou City, Zhejiang, 325000 P.R.China
Doi:10.1021/jo00028a012
(1992)Doi:10.1016/j.molstruc.2012.02.054
(2012)Doi:10.1055/s-0031-1290610
(2012)Doi:10.1271/bbb.110829
(2012)Doi:10.1021/jm00086a006
(1992)Doi:10.1021/ja00026a026
(1991)
