Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1458 - 1461 (1990)
Update date:2022-08-03
Topics:
Volchkov, N. V.
Zabolotskikh, A. V.
Ignatenko, A. V.
Nefedov, O. M.
Fluorochlorocarbene, generated from CHCl2F using phase transfer catalysis, reacts with indene, cyclopentadiene, and their alkyl derivatives to form 2-fluoronaphthalenes or fluorobenzenes in 9-60percent yield.Reactions proceed through formation of unstable fluorochlorocyclopropanes, which rearrange selectively independently of their stereochemical configuration into the corresponding aromatic fluorides with elimination of HCl.
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