REACTION OF FLUOROCHLOROCARBENE WITH CYCLOPENTADIENE, INDENE, AND THEIR ALKYL DERIVATIVES BY PHASE TRANSFER CATALYSIS

DOI: 10.1007/BF00957859

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1458 - 1461 (1990)

Update date:2022-08-03

Topics:

Authors:

Volchkov, N. V.

Zabolotskikh, A. V.

Ignatenko, A. V.

Nefedov, O. M.

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Article abstract of DOI:10.1007/BF00957859

Fluorochlorocarbene, generated from CHCl2F using phase transfer catalysis, reacts with indene, cyclopentadiene, and their alkyl derivatives to form 2-fluoronaphthalenes or fluorobenzenes in 9-60percent yield.Reactions proceed through formation of unstable fluorochlorocyclopropanes, which rearrange selectively independently of their stereochemical configuration into the corresponding aromatic fluorides with elimination of HCl.

Full text of DOI:10.1007/BF00957859

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