PREPARATION AND REACTIONS OF trans- (R = Me, Ph or C6H4Me-p)

DOI: 10.1016/S0022-328X(00)99112-5

Source and publish data:

Journal of Organometallic Chemistry p. 261 - 266 (1983)

Update date:2022-07-30

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Authors:

McPherson, Helen

Wardell, James L.

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Article abstract of DOI:10.1016/S0022-328X(00)99112-5

Formation of trans-<(PPh3)2Pt(CH2SR)Cl> (R=Me, Ph or C6H4Me-p) has been achieved by the oxidative addition of ClCH2SR to (PPh3)4Pt in refluxing PhH.The reaction of ClCH2SMe with (PMe2Ph)4Pt led to cis-<(PMe2Ph)2PtCl2>.The reaction of trans-<(PPh3)2Pt(CH2S

Full text of DOI:10.1016/S0022-328X(00)99112-5

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Product name:trans-[(PPh₃)2PtCl₂]*CH₂Cl₂

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