Total synthesis of (+)-leukotriene B4 methyl ester and its 5-epimer from (R)-glycidol

DOI: 10.1016/S0040-4020(01)89730-1

Source and publish data:

Tetrahedron p. 7279 - 7286 (1991)

Update date:2022-08-03

Topics:

Authors:

Avignon-Tropis

Treilhou

Pougny Pougny

Frechard-Ortuno

Linstrumelle

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Article abstract of DOI:10.1016/S0040-4020(01)89730-1

The Pd-Cu coupling reaction of a chiral hydroxy-(E,E)-iododiene with a racemic acetylenic alcohol followed by reduction of the dienyne leads to the desired (Z,E,E) geometry and allows synthesis of LTB₄ and its 5-epimer after separation of diast

Full text of DOI:10.1016/S0040-4020(01)89730-1

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