A significant barrier to 1,2 hydrogen migration in singlet 1-phenylethylidene. A laser flash photolysis study

DOI: 10.1021/ja00029a027

Source and publish data:

Journal of the American Chemical Society p. 966 - 973 (1992)

Update date:2022-07-30

Topics:

Authors:

Sugiyama, Michelle H.

Celebi, Sol

Platz, Matthew S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00029a027

Laser flash photolysis of 1-phenyldiazoethane in heptane releases 1-phenylethylidene which can be intercepted with pyridine to form an ylide (λ_max> = 475 nm). Oxygen trapping experiments indicate that relaxation of singlet 1-phenylethylidene to

Full text of DOI:10.1021/ja00029a027

Products guided by the article

Product name:Pyridinium, 1-[4-(trifluoromethyl)phenyl]ethylide

Cas No:137871-17-1

R&D Labs maybe for 137871-17-1

Changzhou Sunsheng Chem Co., Ltd

Contact:+1-(989)-854-0648

Address:No. 28 Yinshan Rd., Xixiashu Industrial Park
Tractus Company Limited

Contact:+852-8198 2399

Address:9E, Leapont Industrial Building, 18-28 Wo Liu Hang Road, Shatin, New Territories, Hong Kong
Yixing Bluwat Chemicals Co., Ltd.

Contact:+86 510 87821568

Address:Yongan Road, Yixing Chemical Industrial Park, Yixing, Jiangsu, China
enantiotech corporation ltd

Contact:+86-0760-85282375

Address:zhongjing road,zhongshan torch hi-tech industrial development zone
Zhejiang Rongkai Chemical Technology Co.,Ltd.

Contact:+86-578-8185786

Address:Shangjiang Industrial Zone,Suichang

Relevant to this article

Chemical synthesis and biological evaluation of ω-hydroxy polyunsaturated fatty acids

Doi:10.1016/j.bmcl.2016.12.002
(2017)
Water mediated ligand functional group cooperativity: The contribution of a methyl group to binding affinity is enhanced by a COO^- group through changes in the structure and thermodynamics of the hydration waters of ligand-thermolysin complexes

Doi:10.1021/jm300472k
(2012)
A tunable route for the synthesis of azomethine imines and β-aminocarbonyl compounds from alkenes

Doi:10.1021/ja305491t
(2012)
Synthesis of indolylquinolines, indolylacridines, and indolylcyclopenta[b] quinolines from the Baylis-Hillman adducts: An in situ [1,3]-sigmatropic rearrangement of an indole nucleus to access indolylacridines and indolylcyclopenta[b]quinolines

Doi:10.1021/jo301313m
(2012)
Synthesis, spectroscopic characterization, and molecular structure of triphenyl butene derivatives containing a cyclopentadienyl iron unit

Doi:10.1016/j.ica.2012.03.056
(2012)
A convergent, unified approach to functionalized fluoro- and trifluoromethyl alkenes

Doi:10.1021/ol3023903
(2012)

Article Doi