A significant barrier to 1,2 hydrogen migration in singlet 1-phenylethylidene. A laser flash photolysis study

DOI: 10.1021/ja00029a027

Source and publish data:

Journal of the American Chemical Society p. 966 - 973 (1992)

Update date:2022-07-30

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Authors:

Sugiyama, Michelle H.

Celebi, Sol

Platz, Matthew S.

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Article abstract of DOI:10.1021/ja00029a027

Laser flash photolysis of 1-phenyldiazoethane in heptane releases 1-phenylethylidene which can be intercepted with pyridine to form an ylide (λ_max> = 475 nm). Oxygen trapping experiments indicate that relaxation of singlet 1-phenylethylidene to

Full text of DOI:10.1021/ja00029a027

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