Novel 1,4-Asymmetric Induction in Nucleophilic 1,2-Additions to Chiral γ-Amino Enals

DOI: 10.1039/c39910001309

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1309 - 1311 (1991)

Update date:2022-08-03

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Authors:

Reetz, M. T.

Wang, Fan

Harms, K.

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Article abstract of DOI:10.1039/c39910001309

γ-Dibenzylamino enals 3a with the E-configuration derived from amino acids 1 react diastereoselectively with cuprates in an unexpected 1,2-manner, while the analogues 3b with the Z-configuration undergo diastereoselective additions with organolithium reagents.

Full text of DOI:10.1039/c39910001309

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