Organic and Biomolecular Chemistry p. 7443 - 7446 (2016)
Update date:2022-08-02
Topics:
Tu, Daoquan
Cheng, Xiuzhi
Gao, Yadong
Yang, Panpan
Ding, Yousong
Jiang, Chao
A direct C-2 methylation reaction of indoles bearing a readily removable N-2-pyrimidyl moiety as a site-specific directing group has been developed with a palladium catalyst. This reaction relied on the use of KF to promote efficient methylation. A moderate to good yield was achieved in a range of indole substrates.
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